Deep Impurity Doping

Deep impurity doping is a semiconductor engineering method that introduces selected impurity atoms to create electronic states deep within a material’s bandgap, enabling precise control of carrier behavior. Unlike shallow dopants, these impurities can trap electrons or holes, compensate native charge carriers, and promote recombination by interacting with defects and energy levels under specific electrical or thermal conditions. This control supports the design of resistive regions, carrier lifetime adjustment, radiation-sensitive devices, and engineered switching or sensing components. Understanding deep-level states helps researchers relate dopant concentration and activation to conductivity, stability, and device performance.

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Education

JoVE Science Education - Chemistry

Glovebox and Impurity Sensors

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2023

Source: Tamara M. Powers, Department of Chemistry, Texas A&M University The glovebox provides a straightforward means to handle air- and moisture-sensitive solids and liquids. The glovebox is what it sounds like: a box with gloves attached to one or more sides, which allows the user to perform manipulations within the glovebox under an inert atmosphere. For manipulations under inert atmospheres, chemists can choose between Schlenk or high-vacuum techniques and a glovebox. Schlenk and...

Research

JoVE Journal - Chemistry

Synthesis and Characterization of Fe-doped Aluminosilicate Nanotubes with Enhanced Electron Conductive Properties

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Cited by 3 •

2016

Here, we present a protocol to synthesize and characterize Fe-doped aluminosilicate nanotubes. The materials are obtained by either sol-gel synthesis upon addition of FeCl3•6H2O to the mixture containing the Si and Al precursors or by post-synthesis ionic exchange of preformed aluminosilicate nanotubes.

Monolayer Contact Doping of Silicon Surfaces and Nanowires Using Organophosphorus Compounds

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Cited by 9 •

2013

A detailed procedure for surface doping of Silicon interfaces is provided. The ultra-shallow surface doping is demonstrated by using phosphorus containing monolayers and rapid annealing process. The method can be used for doping of macroscopic area surfaces as well as nanostructures.

Synthesis of Non-uniformly Pr-doped SrTiO3 Ceramics and Their Thermoelectric Properties

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Cited by 4 •

2015

A protocol for the synthesis and processing of polycrystalline SrTiO3 ceramics doped non-uniformly with Pr is presented along with the investigation of their thermoelectric properties.

Synthesis and Functionalization of Nitrogen-doped Carbon Nanotube Cups with Gold Nanoparticles as Cork Stoppers

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Cited by 10 •

2013

We discussed the synthesis of individual graphitic nanocups using a series of techniques including chemical vapor deposition, acid oxidation and probe-tip sonication. By citrate reduction of HAuCl4, the graphitic nanocups were effectively corked with gold nanoparticles due to the chemically reactive edges of the cups.

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