1.5
Systematic Error: Methodological and Sampling Errors
Systematic errors, depending on their source, are of four types – sampling, instrumental, method, and personal errors.
Sampling errors occur due to improper sampling methods, which leads to variation between replicate samples. A refined sampling strategy minimizes these errors.
Instrumental errors arise from defective instruments or faulty calibrations These errors can be eliminated by periodic calibration.
Method errors stem from limitations in the analytical method, non-ideal behavior of reagents, and invalid assumptions. These errors can be mitigated using standard reference materials, blank tests, or conducting a parallel independent analysis.
Furthermore, personal errors are a result of carelessness and the limited abilities of analysts. These can be minimized via systematic, attentive laboratory work, and automated procedures.
If the magnitude of absolute error is independent of the sample size, then it is a constant error. However, if it varies systematically with the sample size, it is a proportionate error.
In the case of systematic errors, the sources can be identified, and the errors can be subsequently minimized by addressing these sources. According t…